ASTM D341.pdf

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An American National Standard

Designation: D 341 – 03

Standard Test Method for

Viscosity-Temperature Charts for Liquid Petroleum Products1 This standard is issued under the fixed designation D 341; the number immediately following the designation indicates the year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript epsilon (e) indicates an editorial change since the last revision or reapproval. This standard has been approved for use by agencies of the Department of Defense.

2.2 ASTM Adjuncts: Adjunct D 341, Viscosity-Temperature Charts 1–73

1. Scope 1.1 The kinematic viscosity-temperature charts (see Figs. 1 and 2) covered by this standard are a convenient means to ascertain the kinematic viscosity of a petroleum oil or liquid hydrocarbon at any temperature within a limited range, provided that the kinematic viscosities at two temperatures are known. 1.2 The charts are designed to permit petroleum oil kinematic viscosity-temperature data to plot as a straight line. The charts here presented provide a significant improvement in linearity over the charts previously available under Method D 341 – 43. This increases the reliability of extrapolation to higher temperatures.

3. Technical Hazard 3.1 Caution—The charts should be used only in that range in which the hydrocarbon or petroleum fluids are homogeneous liquids. The suggested range is thus between the cloud point at low temperatures and the initial boiling point at higher temperatures. The charts provide improved linearity in both low kinematic viscosity and at temperatures up to 340°C (approximately 650°F) or higher. Some high-boiling point materials can show a small deviation from a straight line as low as 280°C (approximately 550°F), depending on the individual sample or accuracy of the data. Reliable data can be usefully plotted in the high temperature region even if it does exhibit some curvature. Extrapolations into such regions from lower temperatures will lack accuracy, however. Experimental data taken below the cloud point or temperature of crystal growth will generally not be of reliable repeatability for interpolation or extrapolation on the charts. It should also be emphasized that fluids other than hydrocarbons will usually not plot as a straight line on these charts.

2. Referenced Documents 2.1 ASTM Standards: 2 D 445 Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (the Calculation of Dynamic Viscosity) 1 These charts are under the jurisdiction of ASTM Committee D02 on Petroleum Products and Lubricants and are the direct responsibility of Subcommittee D02.07 on Flow Properties. Current edition approved Dec. 1, 2003. Published January 2004. Originally approved in 1932. Last previous edition approved in 1998 as D 341–93 (1998). 2 For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [email protected] For Annual Book of ASTM Standards volume information, refer to the standard’s Document Summary page on the ASTM website.

3 Available from ASTM International Headquarters. Order Adjunct No. ADJD0341CS.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.

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D 341 – 03

FIG. 1 Facsimile of Kinematic Viscosity-Temperature Chart I High Range (Temperature in degrees Celsius)

2

D 341 – 03

FIG. 2 Facsimile of Kinematic Viscosity-Temperature Chart II Low Range (Temperature in degrees Celsius)

4. Description 4.1 The charts are designed to permit kinematic viscositytemperature data for a petroleum oil or fraction, and hydrocarbons in general, to plot as a straight line over a wide range. Seven charts are available as follows:3

Temperature: −100 to +700°F Size: 520 by 820 mm (20.5 by 32.25 in.) Pad of 50 ADJD034106 Chart VII—Kinematic Viscosity, Middle Range: Kinematic Viscosity: 3 to 200 000 cSt Temperature: −40 to +150°C Size: 217 by 280 mm (8.5 by 11.0 in.) Pad of 50 ADJD034107

Chart I—Kinematic Viscosity, High Range: Kinematic Viscosity: 0.3 to 20 000 000 cSt Temperature: −70 to +370°C Size: 680 by 820 mm (26.75 by 32.25 in.) Pad of 50 ADJD034101 Chart II—Kinematic Viscosity, Low Range: Kinematic Viscosity: 0.18 to 6.5 cSt Temperature: −70 to +370°C Size: 520 by 820 mm (20.5 by 32.25 in.) Pad of 50 ADJD034102 Chart III—Kinematic Viscosity, High Range: Kinematic Viscosity: 0.3 to 20 000 000 cSt Temperature: −70 to +370°C Size: 217 by 280 mm (8.5 by 11.0 in.) Pad of 50 ADJD034103 Chart IV—Kinematic Viscosity, Low Range: Kinematic Viscosity: 0.18 to 6.5 cSt Temperature: −70 to +370°C Size: 217 by 280 mm (8.5 to 11.0 in.) Pad of 50 ADJD034104 Chart V—Kinematic Viscosity, High Range: Kinematic Viscosity: 0.3 to 20 000 000 cSt Temperature: −100 to +700°F Size: 680 by 820 mm (26.75 by 32.25 in.) Pad of 50 ADJD034105 Chart VI—Kinematic Viscosity, Low Range: Kinematic Viscosity: 0.18 to 3.0 cSt

4.2 Charts I, II, V, and VI are preferred when convenience and accuracy of plotting are desired. Chart VII is the middle range section of Chart I at somewhat reduced scale. It is provided for convenience in connection with reports and data evaluation. Charts III and IV are the same as Charts I and II and are provided in greatly reduced scale for convenience in connection with reports or quick evaluation of data. These latter charts are not recommended for use where the most accurate interpolations or extrapolations are desired. 5. Procedure 5.1 Plot two known kinematic viscosity-temperature points on the chart. Draw a sharply defined straight line through them. A point on this line, within the range defined in Section 3, shows the kinematic viscosity at the corresponding desired temperature and vice versa.4

4 If the kinematic viscosities are not known, they should be determined in accordance with Test Method D 445.

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D 341 – 03 5.2 Alternatively, the interpolated and extrapolated kinematic viscosities and temperatures may be calculated as described in Annex A1, within the range identified for the charts in Section 3.

two points are not sufficiently far apart, experimental errors in the kinematic viscosity determinations and in drawing the line may seriously affect the accuracy of extrapolated points, particularly if the difference between an extrapolated temperature and the nearest temperature of determination is greater than the difference between the two temperatures of determination. In extreme cases, an additional determination at a third temperature is advisable.

6. Extrapolation 6.1 Kinematic viscosity-temperature points on the extrapolated portion of the line, but still within the range defined in Section 3, are satisfactory provided the kinematic viscositytemperature line is located quite accurately. For purposes of extrapolation, it is especially important that the two known kinematic viscosity-temperature points be far apart. If these

7. Keywords 7.1 charts; kinematic viscosity; MacCoull; viscosity; viscosity-temperature charts

ANNEX (Mandatory Information) A1. MATHEMATICAL EQUATIONS

A1.1 The complete design equation for the chart as given in Appendix X1.1 is not useful for inter-calculations of kinematic viscosity and temperature over the full chart kinematic viscosity range. More convenient equations5 that agree closely with the chart scale are given below. These are necessary when calculations involve kinematic viscosities smaller than 2.0 (mm2/s (cSt). log log Z 5 A 2 B log T

(A1.1)

Z 5 n 1 0.7 1 exp ~21.47 2 1.84n 2 0.51n 2!

(A1.2)

n 5 [Z 2 0.7] 2 exp ~20.7487 2 3.295 [Z 2 0.7] 1 0.6119 [Z 2 0.7]2 2 0.3193 [Z 2 0.7] 3!

(A1.3)

where: log n T

= logarithm to base 10, = kinematic viscosity, mm2/s (or cSt), = temperature, K (or t + 273.15, where t is °C), and A and B = constants. A1.2 Inserting Eq A1.2 into Eq A1.1 will permit solving for the constants A and B for a fluid in which some of the experimental kinematic viscosity data fall below 2.0 mm2/s (cSt). This form can also be used to calculate the temperature associated with a desired kinematic viscosity. A1.3 Conversely, the kinematic viscosity associated with a stated temperature can be found from the equation determined as in A1.2 by solving for Z in the substituted Eq A1.1, and then subsequently deriving the kinematic viscosity from the value of Z by the use of Eq A1.3.

5 Manning, R. E., “Computational Aids for Kinematic Viscosity Conversions from 100 and 210°F to 40 and 100°C,” Journal of Testing and Evaluation, JTEVA, Vol 2, No. 6, 1974 pp. 522–8.

APPENDIX (Nonmandatory Information) X1. HISTORY OF THE ASTM VISCOSITY-TEMPERATURE CHARTS

X1.2 In 1928, Walther8 published the log-log Eq X1.1 without the constant, and in 1931, the log-log equation with a constant of 0.8.

X1.1 The forerunner of these charts was published by Neil MacCoull.6 His continuation of the study of these charts resulted in publication in 19277 of the chart based on log

log ~cSt 1 0.7! 5 A 2 B log T

(X1.1)

X1.3 The present MacCoull-Wright charts are based largely on the work of MacCoull, Wright, and ASTM Subcommittee D02.07.

An ASTM committee undertook study of this chart at that time, resulting in the first ASTM chart publication in 1932 using a constant of 0.8 in the equation. The constant was allowed to vary in charts published after 1937.

8 Walther, C., “The Variation of Viscosity with Temperature–I, II, III,” Erdol und Teer, Vol 5, 1928, p. 510, 526, 614. 6 7

MacCoull, N., Lubrication, The Texas Company, New York, June 1921, p. 65. 1927 International Critical Tables, p. 147.

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D 341 – 03 X1.4 The current charts were derived9 with computer assistance to provide linearity over a greater range on the basis of the most reliable of modern data. The general relationship is: log log Z 5 A 2 B log T

Z Z Z Z Z Z

(X1.2)

where: Z = (v + 0.7 + C − D + E − F + G − H), log = logarithm to base 10, v = kinematic viscosity, mm2/s (or cSt), T = temperature, K (or t + 273.15, where t is C), A and B = constants, C = exp (−1.14883 − 2.65868v), D = exp (−0.0038138 − 12.5645v), E = exp (5.46491 − 37.6289v), F = exp (13.0458 − 74.6851v), G = exp (37.4619 − 192.643v), and H = exp (80.4945 − 400.468v). X1.4.1 Terms C through H are exponentials on the natural base e since this simplifies computer programming. Eq X1.1 uses logarithms to the base 10 for general convenience when used in short form. X1.4.2 The limits of applicability are listed below:

= = = = = =

(v + 0.7) (v + 0.7 + C) (v + 0.7 + C − D) (v + 0.7 + C − D + E) (v + 0.7 + C − D + E − F + G) (v + 0.7 + C − D + E − F + G − H)

2 3 107 2 3 107 2 3 107 2 3 107 2 3 107 2 3 107

to to to to to to

2.00 1.65 0.90 0.30 0.24 0.21

cSt cSt cSt cSt cSt cSt

X1.5 It is obvious that Eq X1.1 in the simplified form: log log (v + 0.7) = A − B log T will permit kinematic viscosity calculations for a given fluid in the majority of instances required. The constants A and B can be evaluated for a fluid from two data points. Kinematic viscosities or temperatures for other points can then be readily calculated. X1.6 Older literature refers to a value called the ASTM Slope. It should be noted that this value is not the value of B given in Eq X1.2. The ASTM Slope was originally obtained by physically measuring the slope of the kinematic viscositytemperature data plotted on the older charts given in Test Method D 341 – 43. The kinematic viscosity and temperature scales were not made to the same ratios in Test Method D 341 – 43. The improved charts given here utilize even different scale ratios for dimensional convenience and a different constant (0.7) from the older charts; consequently, the original ASTM Slope is not numerically equivalent to B in Eq X1.1 from any of the new charts, nor directly convertible from Eq X1.1.

9 Wright, W. A., “An Improved Viscosity-Temperature Chart for Hydrocarbons,” Journal of Materials, Vol 4, No. 1, 1969, pp. 19–27.

ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk of infringement of such rights, are entirely their own responsibility. This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards and should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should make your views known to the ASTM Committee on Standards, at the address shown below. This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above address or at 610-832-9585 (phone), 610-832-9555 (fax), or [email protected] (e-mail); or through the ASTM website (www.astm.org).

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